Had you heard about these fatalities of a laboratory researchers in industrial labs? One in Canada and one in NJ, both apparentl y from exposure to TMS diazomethane.
This ‘Pipeline’ blog has had some excellen t discussions about chemical reaction specific safety during the last year or so.
http://pipeline.corante.com/archives/2009/05/14/tms _diazomethane_update_on_a_fatality.php
Kathy
Kath ryn G. Benedict
Assistant Director, Division of Research Safety
Head, Chemical Safety Section
Univ ersity of Illinois at Urbana-Champaign
katbene**At_Symbol_Here**illinois.edu
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