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Subject: Re: [DCHAS-L] PPE Excuses for Non-Compliance
Date: Saturday, August 1, 2020 at 6:25:09 PM
Author: Joseph DiVerdi <joseph.diverdi**At_Symbol_Here**ColoState.EDU> 		Next by Date:
Subject: Re: [DCHAS-L] neutralizing ammonium sulfide
Date: Sun, 2 Aug 2020 10:07:32 -0600
Author: Joseph DiVerdi

From: Monona Rossol <0000030664c37427-dmarc-request**At_Symbol_Here**LISTS.PRINCETON.EDU>
Subject: Re: [DCHAS-L] neutralizing ammonium sulfide
Date: Sun, 2 Aug 2020 10:18:56 +0000
Reply-To: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU>
Message-ID: 1946609633.326427.1596363536077**At_Symbol_Here**mail.yahoo.com


I think this is called waste treatment and not allowed without a license.  Monona 


-----Original Message-----
From: JOHN L STRAUGHN <0000120dde6ec15c-dmarc-request**At_Symbol_Here**LISTS.PRINCETON.EDU>
To: DCHAS-L <DCHAS-L**At_Symbol_Here**Princeton.EDU>
Sent: Sun, Aug 2, 2020 05:34 AM
Subject: Re: [DCHAS-L] neutralizing ammonium sulfide


I'd try this: small scale, look for sulfur precipitation (may clear with further addition of peroxide), nitrogen gas bubbling and further NOx generation (red-brown fumes, ie. in a hood) possible. Get a recipie that works and share it in glory!
From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU> on behalf of 00000eca7dd1d088-dmarc-request**At_Symbol_Here**LISTS.PRINCETON.EDU <00000eca7dd1d088-dmarc-request**At_Symbol_Here**LISTS.PRINCETON.EDU>
Sent: Friday, July 31, 2020 12:06 PM
To: DCHAS-L**At_Symbol_Here**Princeton.EDU <DCHAS-L**At_Symbol_Here**Princeton.EDU>
Subject: Re: [DCHAS-L] neutralizing ammonium sulfide
 
You might look into adding hydrogen peroxide, perborate or some persulfate derivative.

Dan



-----Original Message-----
From: Nickie Norton <nnorton**At_Symbol_Here**SHEPCHEM.COM>
To: DCHAS-L**At_Symbol_Here**Princeton.EDU
Sent: Fri, Jul 31, 2020 10:35 am
Subject: [DCHAS-L] neutralizing ammonium sulfide

Hi All,
 
We are using ammonium sulfide in excess in a reaction in water.  What is the proper way to dispose of the aqueous ammonium sulfide?  We are concerned that if we add bleach we will make chloramine.  Does anyone have a way to convert the ammonium sulfide to ammonium sulfate?
 
Thank you,
 
Nickie Norton
Research Chemist
The Shepherd Chemical Company
4900 Beech Street
Norwood, OH  45212
nnorton**At_Symbol_Here**shepchem.com
513-842-9332
 
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