On a similar note, I was once shown a high speed video of a shaped
charge penetrating a crew vehicle bearing aluminum armor, followed
immediately by discharge of halon. A few milliseconds after the halon
discharge there was an explosion originating in the vehicle atmosphere.
The project manager was trying to figure out why.
Hot aluminum particles/vapor plus halon go boom!
Dave Lane
Principal
Clavis Technology Development
On 7/9/20 10:16 AM, Jack Reidy wrote:
> All,
>
> I forwarded this to our Chemistry Department and received an interesting reply from Prof. Bob Waymouth, chair of the department safety committee, about an alternative explanation for the explosion. In the original email he attached an article, which can be found at this link (http://pubsapp.acs.org.stanford.idm.oclc.org/cen/safety/19970317.html?). The text of the email he sent is below:
>
> Thanks for forwarding. The use of reducing metals (Li, Mg, Al) with fluorinated organic compounds is hazardous and as pointed out by authors, there are several examples of explosions. We had previous experience with Grignards of compounds containing trifluoromethyl groups. (See C&E News Letter from 1997). We had attributed the explosion hazard to be due to the high lattice energies of the metal fluorides. I think this a a more likely interpretation than that of the authors, but they do describe previous explosions with Al reducing agents and perflourinated compounds.
>
>>From my quick CRC look (you should check these numbers)
>
> MgF2. Lattice energy -2922 kJ/mol
> AlF3 Lattice energy - 5924 kJ/mol
>
> -----Original Message-----
> From: ACS Division of Chemical Health and Safety On Behalf Of DCHAS Membership Chair
> Sent: Thursday, July 9, 2020 4:49 AM
> To: DCHAS-L**At_Symbol_Here**Princeton.EDU
> Subject: [DCHAS-L] Serious Explosion during Large-Scale Preparation of an Amine by Alane (AlH3) Reduction of a Nitrile Bearing a CF3 Group
>
> Serious Explosion during Large-Scale Preparation of an Amine by Alane (AlH3) Reduction of a Nitrile Bearing a CF3 Group
>
> https://pubs.acs.org/doi/10.1021/acs.chas.0c00045
>
> Here, we wish to report a serious explosion during large-scale preparation of an amine by alane (AlH3) reduction of a nitrile bearing a CF3 group. The accident took place during the reduction of a 1 mol batch of 1-methyl-3-(trifluoromethyl)-1H-pyrazole-5-carbonitrile. At the stage of decomposition of the reaction mixture after reduction with MeOH, the reactor was destroyed by detonation; one researcher was seriously harmed by shatters and burnt by flames. This Case Study describes this incident in detail and discusses how we can prevent similar incidents.
>
> ---
> For more information about the DCHAS-L e-mail list, contact the Divisional membership chair at membership**At_Symbol_Here**dchas.org Follow us on Twitter **At_Symbol_Here**acsdchas
>
> ---
> For more information about the DCHAS-L e-mail list, contact the Divisional membership chair at membership**At_Symbol_Here**dchas.org
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