Dewars are very different than cylinders in that they need to vent to maintain the cold temperatures. This can be continuous creating a asphysiating environmentt. I don't see this as an issue with toxic or highly toxic cylinders that are leak tested prior to transport.
Eugene Ngai
Chemically Speaking LLC
www.chemicallyspeakingllc.com
-----Original Message----- Preferably a service elevator, but could be any elevator. Do need an operator key to keep others from riding along. The link below has a short concise section of cylinder transport in elevators. However, I can‰??t find any binding document that is specific to elevator transport. Might be a CGA doc. https://www.airproducts.com/~/media/Files/PDF/company/safetygram-27.pdf Thank you, Yaritza Brinker From: ACS Division of Chemical Health and Safety Eugene Ngai From: ACS Division of Chemical Health and Safety Our academic institution had a similar ruling when transporting gas cylinders and dewars, especially LN2. Most of our hazardous chemicals were transported in hand carry totes, with a maximum size of 1 L bottle, Max 6 bottles. I don‰??t think there was a passenger limitation for those transports. On Wed, Jan 15, 2020 at 4:06 PM Stella Julia Sommer <0000071592c679d2-dmarc-request**At_Symbol_Here**lists.princeton.edu Sent from my iPhone Begin forwarded message: "5003.10.4 Elevators utilized to transport hazardous materials. This is a very concerning. Thank you! Stella Sommer --- For more information about the DCHAS-L e-mail list, contact the Divisional membership chair at membership**At_Symbol_Here**dchas.org Electronic Transmission Confidentiality Notice The information contained in this electronic transmission is private, confidential, the property of the sender, and intended for the use of the recipient(s), only. If you are not the addressee, any disclosure, copying, distribution or use of this information for any purpose is strictly prohibited. If you have received this information in error, please notify the sender, YBrinker**At_Symbol_Here**fele.com, immediately by e-mail and then delete this message. Thank you. --- ---
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From: ACS Division of Chemical Health and Safety
Sent: Thursday, January 16, 2020 1:06 PM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: Re: [DCHAS-L] Transporting Hazardous Chemicals on an Elevator - Surprising Statement California Fire Code
260.827.5402
Sent: Thursday, January 16, 2020 7:44 AM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: Re: [DCHAS-L] Transporting Hazardous Chemicals on an Elevator - Surprising Statement California Fire Code
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I‰??m new to this issue. To me there are many laboratories above or below the 1st floor. How are the cylinders moved to them? Freight elevator? I assume that this regulation is for regular passenger elevators. A 1 lb water capacity is a lecture bottle which is 440 cc (440 gms water capacity). For any good MOCVD research a cylinder containing at least 10 times that amount of arsine or phosphine is required for purity reasons. Otherwise it is a waste of time.
I was shocked to audit a University lab in the US that had graduate students physically slide/bump 200 lb cylinders of a highly toxic reactive gas up 2 flights of stairs since there was not an elevator. There was no option.
I assume that the transport of these cylinders are done after leak checking using a electronic leak detector. A leak to spontaneously occur during the brief time it is in the elevator is impossible without some severe physical event.. I did drop testing of 49 liter cylinder valves without a cylinder cap from a height of 7 ft and never succeeded in loosening or breaking the valve.
Chemically Speaking LLC
www.chemicallyspeakingllc.com<https://nam12.safelinks.protection.outlook.com/?url=http%3A%2F%2Fwww.chemicallyspeakingllc.com&data=02%7C01%7C%7C64254eaba30749abfac608d79a81dfe8%7C994c3e8bb42845fb8640593ef0303f7f%7C0%7C0%7C637147754920915989&sdata=515xsNGRSixVxBBpRyZppcunds%2Bdfg5m94m8JGVou9s%3D&reserved=0>
Sent: Wednesday, January 15, 2020 9:30 PM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: Re: [DCHAS-L] Transporting Hazardous Chemicals on an Elevator - Surprising Statement California Fire Code
From: Stella Julia Sommer
Date: January 15, 2020 at 10:30:45 AM PST
To: LISTSERV**At_Symbol_Here**listserv.med.cornell.edu
Subject: Transporting Hazardous Chemicals on an Elevator - Surprising Statement California Fire Code •ÈÀ Dear all, I had an interesting conversation about transporting hazardous chemicals this morning. My co-worker mentioned that the CA Fire Code would allow the transport of a certain quantity of hazardous chemicals when someone is riding the elevator at the same time. I was skeptical, so I looked it up.
5003.10.4.1. When transporting hazardous materials, elevators shall have no other passengers other than the
individual(s) handling the chemical transport cart.
5003.10.4.2. Hazardous materials liquid containers shall have a maximum capacity of 20 liters (5.28 gal).
5003.10.4.3. Toxic and highly-toxic gases shall be limited to a container of a maximum water capacity of 1 pound."
I would appreciate your comments!
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