From: Mark Bachrach <markbachrach2015**At_Symbol_Here**U.NORTHWESTERN.EDU>
Subject: Re: [DCHAS-L] Laboratory Gas Detection
Date: Tue, 12 Mar 2019 10:00:42 -0400
Reply-To: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU>
Message-ID: CADv-0JZ3oX3M9_d=cz0cbnjcSMtxnZq28FcTNULWHnDDvBe5=g**At_Symbol_Here**mail.gmail.com
In-Reply-To <2F386B2B-1BFA-4F10-B80D-17A586E15B70**At_Symbol_Here**dal.ca>


From our O2 alarm policy currently making its way through our policy committee:


1. Oxygen sensors/detectors with low and high-level alarms will be located in areas that present a potential asphyxiation hazard due to the presence of manifolded or central liquid nitrogen or other asphyxiant gases.

2. Before any large volume container of compressed gas or cryogenic liquid is used, Environmental Health and Safety must be consulted to determine the need for oxygen detectors and oxygen depletion alarms. Environmental Health and Safety will perform the worst-case scenario calculation assuming the entire volume of container contents are released. If the final oxygen concentration is lower than 18%, oxygen sensors and alarms should be placed.. The calculation to be used is:

Final O2 concentration = 20.9 - 20.9*(Vgas/Vroom)

where Vgas = volume gas released in cubic meters

Vroom = room volume in cubic meters

Liquid

Gas

1L Liquid Nitrogen

0.694 m3 Nitrogen Gas

1L Liquid Helium

0.757 m3 Helium Gas

1L Liquid Argon

0.847 m3 Argon Gas

3. Oxygen depletion alarms should not only sound locally. All alarms should be tied into the Facilities Operations building alarm system.

4. The placement of the sensors should also be determined by EH&S, depending on the nature of the gas.

Gases

Gas Density

Sensor Placement

Argon, Heavy Hydrocarbons

Greater than air

Closer to the ground

Hydrogen, Helium, Methane

Less than air

Near the ceiling

Carbon Monoxide, Nitrogen

Similar to air

At or near breathing level (4 to 6 ft. from the floor)

The sensor should be placed near the most probable location for a gas leak. Whenever possible, the read-out panel or a strobe should be placed in a safe area outside the room. The alarm must be audible both by the location of the read-out panel and by the sensor.

On Tue, Mar 12, 2019 at 9:49 AM Stephen Beaton <Steve.Beaton**At_Symbol_Here**dal.ca> wrote:

Hi all,

I am researching best practice for fixed gas detection in laboratories in the university setting.. There are certainly a number of variables to consider. Does anyone have guidelines/ standards/ decision-trees to establish whether detectors for flammable, oxygen-depleting and toxic gases are required in the laboratory?

Thanks in advance

Steve

Stephen Beaton, MSc, CHO, CRSP
Chemical Safety Manager

Environmental Health and Safety Office
902.494.1934 | steve.beaton**At_Symbol_Here**dal.ca
DALHOUSIE UNIVERSITY

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