I sent the question on to our Geo/chemist & this was his reply. Hope it helps. Kim Auletta Lab Safety Specialist EH&S Z=6200 kauletta**At_Symbol_Here**notes.cc.sunysb.edu 632-3032 ----- Forwarded by Kim Auletta/Admin on 06/14/2007 07:42 AM ----- John Parise/CAS 06/14/2007 07:24 AM To Kim Auletta/Admin**At_Symbol_Here**SUNYSB cc Subject Re: Fw: [DCHAS-L] ZnI question Quick reply My guess is heating might lead to hydrolysis - formation of zinc hydroxide and formation of hydroen iodide (ZnI2 + H2O -> Zn(OH)2 + 2HI which then comes off? Acid would drive the reaction towards ZnI2 Try adding acetic (or something else acid that does not react with anything in the system and heating? Actually I just did a google search .... Try this http://academic.evergreen.edu/curricular/matterandmotion/labs%5CZnI.htm I knew I had done this before! About 35 years ago John John B. Parise Professor Department of Geosciences Department of Chemistry State University of New York NY 11794-2100, USA +1-631-632-8196 - office (-8197, -1140, -8158 labs) +1-631-632-8240 (-8140) FAX EPO: John.parise**At_Symbol_Here**sunysb.edu Kim Auletta/Admin wrote on 06/14/2007 07:11:11 AM: > THought I'd bounce this email question to you - any thoughts on her problem? > > Kim Auletta > Lab Safety Specialist > EH&S Z=6200 > kauletta**At_Symbol_Here**notes.cc.sunysb.edu > 632-3032 > ----- Forwarded by Kim Auletta/Admin on 06/14/2007 07:09 AM ----- > > Debbie Decker> Sent by: DCHAS-L Discussion List > > 06/13/2007 09:14 PM > > Please respond to > Debbie Decker > > To > > DCHAS-L**At_Symbol_Here**LIST.UVM.EDU > > cc > > Subject > > [DCHAS-L] ZnI question > > Greetings: > > Please excuse the cross-posting - I need to cast a wide net. I've > received the following question from a researcher in the Geology > department. > > "I am using Zinc Iodide as a heavy liquid in my current lab procedure. > I would like to re-use it but I am having trouble recycling it, I > dilute it during my procedure and I am having difficulty distilling it > back down to the desired specific gravity. I have built simple > distilling apparatus (heating mantle, boiling flask and graham > condenser) but the vapor that comes off the diluted zinc iodide is > brown/purple and then a metallic film accumulates on the interior of the > condenser. So, it seems like I am distilling more than water. It > produces this purple vapor even at temperatures well below boiling" > > I think she's subliming off the iodine that then plates out on the cool > surfaces of the condenser. But I don't have any creative ideas that > will help her re-use the ZnI solution. > > Thanks for your help, > Debbie > ----------------------- > Debbie M. Decker, Campus Chemical Safety Officer > Environmental Health and Safety > University of California, Davis > 1 Shields Ave. > Davis, CA 95616 > (530)754-7964/(530)752-4527 (FAX) > dmdecker**At_Symbol_Here**ucdavis.edu > Co-Conspirator to Make the World A > Better Place -- Visit www.HeroicStories.com and join the conspiracy
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